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Describe the differences between the reaction quotient and equilibrium constant

The reaction quotient and the equilibrium constant are both essential indicators of a chemical reaction’s progress toward equilibrium; however, they are calculated differently and carry distinct meanings.

The reaction quotient, denoted as QQ, is determined using the same formula as the equilibrium constant, KK, but it employs the concentrations of reactants and products at any point in time during the reaction instead of at equilibrium. The value of QQ can help predict the direction in which the reaction will proceed. Specifically, if QQ is greater than KK, the reaction will favor the formation of reactants in order to reach equilibrium. Conversely, if QQ is less than KK, the reaction will favor the formation of products.

The equilibrium constant, KK, represents the ratio of the concentrations of products to reactants when the reaction has reached equilibrium. It is calculated using the equilibrium concentrations of all species involved in the reaction. Importantly, KK is a constant for a specific reaction at a given temperature and does not depend on the initial concentrations of the reactants and products. The value of KK can also be utilized to calculate the concentrations of reactants and products at equilibrium and to compare the relative strengths of acids and bases.

In summary, both the reaction quotient and the equilibrium constant are vital for understanding a chemical reaction’s progression toward equilibrium. The reaction quotient, QQ, reflects concentrations at any moment during the reaction and indicates the direction of the reaction, while the equilibrium constant, KK, is based solely on concentrations at equilibrium and remains constant for a particular reaction at a specified temperature.

Answered by: Dr. Harriet Collins
A-Level Chemistry Tutor
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